谢美华
E-mail:meihuaxie@163.com
phone:(+86)-553-3869310
所受教育
学士(1991年)安徽师范大学
硕士(1994年)安徽师范大学
博士(2003年)浙江大学
职称职位
1994年-现在 安徽师范大学 研究实习员 助理研究员 副研究员 教授
2005年3月-2006年3月 香港中文大学 博士后研究员
2004年7月-现在 硕士生导师
2005年 安徽省高校中青年优秀骨干教师
2010年 安徽省学术和技术带头人后备人选
2010年4月-现在 博士生导师
主持项目
1.“贫电子炔烃的加成反应及其在有机合成中的应用研究”,国家自然科学基金,2012年1月-2015年12月,项目负责人(21272004)
2.“有机金属试剂在共轭烯炔类化合物的立体选择性合成中的应用”,国家自然科学基金,2008年1月-2010年12月,项目负责人(20772001)
3.“炔基砜的碳金属化反应及其在多取代烯烃合成中的应用”,国家自然科学基金,2007年1月-2009年12月,项目负责人(20672001)
4.有机金属试剂与官能化炔烃的加成反应及其在多取代烯烃合成中的应用 安徽省教委基金,2005年1月-2006年12月,项目负责人(2005KJ129)
5.官能化的烯基金属试剂的制备及其在多取代烯烃的立体选择性合成中的应用 安徽省教委基金,2003年1月-2004年12月,项目负责人
研究领域
金属有机化学
有机合成
讲授课程
有机化学
高等有机化学
基础化学实验
综合化学实验
获奖情况
王绍武,叶钟文,沈富仁,谢美华 等,“镧系金属配合物的研究-合成、性质与结构”,1998 年 安徽省高等学校科技进步一等奖
王绍武,马怀柱,叶钟文,沈富仁,谢美华 “稀土金属配合物的研究-合成、性质与结构”,2000 年 安徽省自然科学二等奖
发表论文
1.Fang Kuang, Xie Meihua*, Zhang Zhannan, Ning Peng, Shu Guanying “Nickel-catalyzed cross-coupling reaction of acetylenic sulfones with alkynyl Grignard reagents: a facile method for the preparation of unsymmetrical 1,3-diynes” Tetrahedron Lett. 2013, 54, 3819-3821.
2.Xie Meihua*, Li Ming, Liu Changqing, Zhang Jitan, Feng Chengyou “Facile Regioselective Synthesis of 5-Hydroxy-4,5-dihydroisoxazoles from Acetylenic Ketones” J. Heterocyclic Chem. 2012, 49, 1462-1465.
3.张继坦,张金花,方旷,束官莹,谢美华* “Fe(III)催化的烯丙醇的Friedel-Crafts环化反应合成多取代茚”有机化学,2012, 32, 1533-1538.
4.Xie Meihua*,Feng Chengyou, Zhang Jitan, Liu Changqing, Fang Kuang, Shu Guanying, Zuo Wansheng“CuI-Catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones: convenient access to tetrasubstituted allylic alcohols” J. Organomet. Chem. 2011, 696, 3397-3401.
5.Xie Meihua*,Zhao Xinyang, Lin Gaofeng, Zhang Jinhua “FeCl3·6H2O-Catalyzed bromocyclization to access functionalized dihydropyrans” Synth. Commun. 2011, 41, 1227–1238.
6.Xie Meihua*,Xie Fadong, Lin Gaofeng, Zhang Jinhua “Convenient synthesis of bis(indolyl)alkanes and bis(pyrrolyl)alkanes by Cu(OTf)2-catalyzed addition of indole and pyrrole to acetylenic sulfone” Tetrahedron Lett. 2010, 51, 1213-1215.
7.Xie Meihua*,Lin Gaofeng, Zhang Jinhua, Li Ming, Feng Chengyou “Regio- and stereoselective synthesis of tetrasubstituted allylic alcohols by three component reaction of acetylenic sulfone, dialkylzinc, and aldehyde” J. Organomet. Chem. 2010, 695, 882-886.
8.Xie Meihua*,Zhang Jinhua, Zhao Xinyang, Lin Gaofeng “An efficient synthesis of polysubstituted dihydropyrans via iodocyclization reaction of allylic alcohols”Chin. J. Chem.2010, 28, 961-966.
9.XieMeihua*,Wang Jialiang, Zhang Wei, Wang Shaowu* “Regio- and stereospecific synthesis of vinyl halides via carbozincation of acetylenic sulfones followed by halogenation” J. Organomet. Chem. 2009, 694, 2258-2262.
10.XieMeihua*,Gu Xiaoxia, Wang Jialiang, Zhang Jinhua, Lin Gaofeng, Wang Shaowu* “Regio- and stereospecific synthesis of polysubstituted alkenes by carbozincation of acetylenic sulfones” Appl. Organomet. Chem. 2009, 23, 258-266.
11.XieMeihua*, Sun Ying, Zhang Wei, Gu Xiaoxia, Zhao Xinyang, Xie Fadong, Wang Shaowu* “Stereoselective synthesis of allylic amines by one-pot tandem reaction of acetylenic sulfone, Grignard reagent, and N-tosylimine” Synth. Commun. 2008, 38, 3785–3796.
12.Gu Xiaoxia, XieMeihua*, Zhao Xinyang, Sun Ying, Zhang Wei, Xie Fadong, Wang Shaowu* “An efficient synthesis of polysubstituted 1,3-enynes from (E)-β-iodovinyl sulfones and terminal alkynes” Chin. J. Chem. 2008, 26, 1625-1629.
13.XieMeihua*,Wang Jialiang, Gu Xiaoxia, Sun Ying, Wang Shaowu* “Highly Regio- and Stereoselective Synthesis of Tetrasubstituted Olefins by Three-Component Tandem Reaction of Allylzinc Bromide, Acetylenic Sulfone and Halohydrocarbon” Org. Lett. 2006, 8, 431-434.
14.Gao Minli, Tang Yong, XieMeihua, Qian Changtao, Xie Zuowei* “Synthesis, Structure, and Olefin Polymerization Behavior of Constrained-Geometry Group 4 Metallacarboranea Incorporating Imido-Dicarbollyl Ligands” Organometallics2006, 25, 2578-2584.
15.XieMeihua*, Liu Li, Wang Jialiang, Wang Shaowu* “Stereoselective synthesis of vinyl sulfones by carbomagnesiation of acetylenic sulfone in the presence of CuCN” J. Organomet. Chem. 2005, 690, 4058-4062.
16.XieMeihua, Huang Xian* “Highly Stereoselective Synthesis of Phenylseleno- and p-Tolylsulfonyl Substituted 1, 3-Dienes from Functionalized Allyl Alcohols” Chin. J. Chem. 2004, 2, 184-186.
17.XieMeihua, Liu Xinyuan, Wang Shaowu*, Liu Li, Wu Yongyong, Yang Gaosheng, Zhou Shuangliu, Sheng Enhong, Huang Zixiang “Synthesis, Structure and Catalytic Activity Comparison of Tris- and Tetracoordinated Lanthanide Amides” Chin. J. Chem.2004, 22, 678-682.
18.XieMeihua, Huang Xian* “Crystal Structures of (Z)-1-Phenyl-1-phenylseleno-2-(p- Tolylsulfonyl)ethene and ( Z)-1, 3-DiPhenyl-3-phenylseleno-2-( p-tolylsulfonyl) -2-propen-1-ol” Chin. J. Struct. Chem. 2004, 23, 543-546.
19.XieMeihua, Huang Xian* “Carbomagnesiation of Acetylenic Sulfones Cataalyzed by CuCN and its Application in the Stereoselective Synthesis of Polysubstitited Vinyl Sulfones” Synlett2003, 4, 477-480.
20.XieMeihua, Huang Xian* “Stereoselective Synthesis of Substituted Allyl Selenide by the Reaction of (E)-3-Selanyl Vinylzirconocene Chloride with Aldehydes or Acyl Chlorides” J. Chem. Research2003, 4, 138.
21.XieMeihua; Wu Luling, Huang Xian* “A Stereoselective Synthesis of Substituted Allyl Alcohol by Three Component Reaction of Actylenic Sulfone, Phenylselenomagnesium Bromide and Ketones” Chinese Chem. Lett. 2003, 14, 887-888.
22.XieMeihua, Wu Luling, Huang Xian* “Stereoselective Synthesis of d -Selanyl Allylic Alcohols by Hydrozirconation of Propargyl Selenides” Chinese Chem. Lett. 2003, 14, 255-256.
23.Wang Shaowu*, Zhou Shuangliu, Sheng Enhong, XieMeihua, Zhang Kehua, Cheng Lin, Feng Yan, Mao Lili, Huang Zixiang “Homolysis of the Eu-N Bond. Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes” Organometallics 2003, 22, 3546-3552.
24.Huang Xian*, XieMeihua “Michael-aldol Tandem reaction of acetylenic sulfone, Phenylselenomagnesium Bromide and Aldehyde. An Efficient Synthesis of Functionalized Allylic alcohols” Org. Lett. 2002, 4, 1331-1334.
25.Huang Xian*, XieMeihua "Highly Stereoselective Three-component Reactions of Phenylselenomagnesium Bromide, Acetyl enic Sulfones and Saturated Aldehydes/Ketones or α,β -Unsaturated Enals or Enones" J. Org. Chem. 2002, 67, 8895.
26.XieMeihua*, Hao Xueshi, Mahuaizhu “Crystal Structure of Bis{1-(2-methoxyethyl) indenyl}dysprosium Chloride” Chinese J. Struct. Chem. 2000, 19, 253-258.
27.XieMeihua,ian Changtao*, Gao Lijuan, Sun Jie “Synthesis and Structure of Barium Complex Containing 2,2,6,6-tetramethyl-3,5-heptanedionate and 1, 10-Phenanthroline Ligands” Chinese J. Struct. Chem. 2000, 19, 419-422.
28.Ma Yun, Qian Changtao*, XieMeihua “Synthesis of furo[3,2-c]- and pyrano[3,2-c]quinolines by lanthanode triflate catalyzed imino-Diels-alder reaction” Chinese J. Chem. 2000, 18, 377-383.